Texas State University
 
Centennial Hall 340/346
Tel: (512) 245-7780/1830
Fax: (512) 245-1892

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Center for Coatings and Bio-Based Technology (CCBT)

The CCBT is a self-supporting center funded by contracts, grants, gifts, and industrial partnerships.

MISSION

The mission of the Center for Coatings and Bio-Based Technology is to be a leading academic organization that provides scientific knowledge for understanding and expanding the technology of coatings and of sustainable raw materials as they relate to paints, coatings, polymers, cement additives, and fibers. Current objectives within the CCBT's core competencies are:
  • To synthesize new types of raw materials for polymers, plasticizers, and crosslinkers of potential value in polymers, coatings, cementitious materials, and fibers.
  • To use sustainable technology in industrial applications
  • To learn principles of physical phenomena critical to coatings and applicable bio-based technologies
  • To improve characterization methods of coatings and bio-based raw materials
  • To increase the cadre of polymer, coatings, and bio-based chemistry professionals by providing support and training in research projects to undergraduate and graduate students, post-doctoral fellows, and visiting scientists

Dr. John Massingill, Adjunct Graduate Faculty in the Chemistry and Biochemistry Department, is Director of the CCBT, building on his experience as a nonacademic department head as Director of the Coatings Research Institute at Eastern Michigan University for seven years. Dr. Massingill has extensive background in polymers and coatings having worked as Executive Director of Paint Research Associates Laboratories, Inc.; and in the Resins Products Department of The Dow Chemical Company prior to joining EMU. Dr. Massingill is the founding Chair of the new (2001) sub-division for Industrial Bio-Based Technology of the Industrial & Engineering division of the American Chemical Society. He is a member of the program committee of the Industrial Oil Products Division of the American Oil Chemists Society and has been elected Chair of the IOP Division for 2004-2005. Biography ; Publications; Research Grants

CCBT LABORATORY AND EQUIPMENT


In addition to the equipment available to IEIS, the following coatings specific equipment is in the CCBT Lab.

TESTING: Dry Film Thickness, Impact, Cross Hatch Adhesion, BK Drying Recorder, Pencil Hardness, Viscometers, Salt Fog Corrosion Chamber, QUV Weatherometer.

PROCESSING: UV Cure Conveyor System , High Speed Disperser, Pigment Roller.

CCBT has the following Polymer Science Cabilities:


Synthesis & Blending - Synthesis of epoxy, alkyd, and polyol resins; Latex polymerizations; Synthesis of Water Dispersible polymers; Formulation of Coatings and Paints; Fire resistant resins; Fire resistant polymers; thermosets.

MassingillMassingill Biography

Director, Center for Coatings and Bio-Based Technology
Institute for Environmental Science and Technology

Texas State University
601 University Drive
San Marcos , TX 78666

Phone: 512-245-9618
FAX: 512-245-1892

E-mail: john.massingill@txstate.edu

Born August 18, 1941 , Lufkin , Texas

EDUCATION

High School: S.F. Austin High School , Houston , Texas
BA, Chemistry, June, 1963 Texas Christian University , Fort Worth , Texas
M.S., Analytical Chemistry, June 1965 Texas Christian University , Fort Worth , Texas
Ph.D., Organic Chemistry, June 1968 Texas Christian University , Fort Worth , Texas

WORK EXPERIENCE

September 2000- Director, Center for Coatings and Bio-Based Technology
Institute for Environmental Science & Technology
Texas State University
San Marcos , TX 78666

Research: Chemical Processes, Fire Retardant Resins, High Temperature Resins, UV Curable Resins and Polyols; Waterborne Epoxy Phosphate Esters; New Alkyd Resins for Architectural and Industrial Paints; Carbohydrate Derivatives for Coatings; Improved Analytical Methods for Determination of Water in Paints; Reactive Diluents for Alkyd and Epoxy Coatings, Low Viscosity Weatherable Aliphatic Epoxy Resins; Toughening of Epoxy Resin; Plasticizers for PVC; Waterborne Inks; Conjugated Soybean Oil, Soy Tackifiers for Adhesives.

May 1, '93-Sept.'00 Director, Coatings Research Institute
Eastern Michigan University
430 West Forest Avenue
Ypsilanti , MI 48197

Research: UV Curable Resins and Polyols; Waterborne Epoxy Phosphate Esters; New Alkyd Resins for Architectural and Industrial Paints; Carbohydrate Derivatives for Coatings; Improved Analytical Methods for Determination of Water in Paints; Reactive Diluents for Alkyd and Epoxy Coatings, Low Viscosity Weatherable Aliphatic Epoxy Resins; Toughening of Epoxy Resin with Vegetable Oils

July1997-June1998 Acting Director, NSF Industry/ University Cooperative Research Center in Coatings. A Research Consortium of 14 Corporations and Government Agencies.

May 93-Oct 94 Executive Director (Joint Appointment with Director, CRI)
Paint Research Associates Laboratories, Inc.
430 West Forest Avenue
Ypsilanti , MI 48197

June1968-April 1993 Development Associate
The Dow Chemical Company
Resin Products R&D
Building B-1603
2301 N. Brazosport Blvd.
Freeport , TX 77541-3257

Assignments: Technical Service and Development, 1984--93; Discovery Research, 1982-84; Resins Research, 1976-82; Hydrocarbon Process Research, 1970-76; Basic Research, 1968-70

1986-1993 Development Associate, responsible for development of formable epoxy resin for container coatings, weatherable epoxy coatings, and low viscosity epoxy resin for low VOC coatings.

1992-1993 Technical Account Manager Valspar Container, Pittsburgh & Kankakee , IL

1984-1993 Technical Account Manager for BASF, Dexter, DeSoto, and 3M. Support for Glidden, Valspar, PPG

1984-1985 Technical Leader, supervise Can and Coil Coating Group Development of Seminars for customers & Dow employees: Epoxy Resin Chemistry, Advanced Epoxy Resin Chemistry, Advancement Catalysis, Practical Resin Advancement.

1984 Development Leader, Specialty Chemicals TS&D Market Research for CPA-04, Determination of Market Value; Market Introduction of CPA-04 to Plaster Industry

1976-83 Research Leader, Resins Research Department

1982-83 Discovery Research, New Products and Processes High Tg Resins, Low Viscosity Resins, New Polymers

1980-82 New Liquid Epoxy Resin Process R&D

1976-80 Epoxy Resin Process Research/Plant Support, improve processes, yields

1970-76 Research Specialist, Hydrocarbon Process Research Department

1972-76, By-Product Utilization, Product and Process R&D

1970-72, Desulfurization of Residual Crude Oil without Hydrogen

1968 Basic Research Department, Sr. Res. Chemist - Benzene from Methane

1968-1970 U.S. Army Chemical Corps, Captain, Edgewood Arsenal, MD Defense Develop. and Eng. Lab, Physical Protection Lab, Air Filtration Branch Developed analytical method for war gas detection- photoionization detector

TEACHING AND COURSE DEVELOPMENT

Instructor, Dow Chemical, 1988-1990, "Championing Innovation"

Customer Short Courses, Dow Chemical, 1984-1993

"Epoxy Resin Chemistry", "Advanced Epoxy Resin Chemistry", "Advancement Catalysis", "Practical Resin Advancement".

Short Course Instructor, Tokyo Japan , "Epoxy Phosphate Ester Coatings", Feb. 1991.

Short Course Instructor, PMSE Short Course, ACS National Meeting San Francisco , "Epoxy Phosphate Ester Coatings", 1992.

PROFESSIONAL SOCIETIES

Sigma Xi, 1968-present

American Chemical Society, 1965-present
ACS Books Department Advisory Board, 1988-1992
ACS National Council, 1979-2001
Committee on Public Affairs, Associate, 2003-present
Committee on Committees (Elected), 1997-2001;
Nominations and Elections committee (Elected), 1990-94
President-Elect Sub-committee, Chairman, 1992
Board of Directors Sub-committee, Chairman 1992,1994
Public Relations Committee, 1983-1991, Chairman, 1988-91
Committee on Professional Relations 1996
Membership Affairs Committee, associate, 1988;
Local Section Activities Comm., 1981-83
Environmental Improvement Committee, associate, 1979

Brazosport Local Section, 1970-1993
Chairman, 1976; Program Chair, 1975; Continuing Education Chair, 1977-78, Councilor, 1979-1987.

Division of Industrial and Engineering Chemistry, 1979-present
Chair, 1986, Councilor, 1988-2001, Program Committee, 1980-2000.
Founder, Sub-Division of Industrial Bio-Based Technology, Chair, 2001-02 .

Division of Polymeric Materials-Science and Engineering, 1980-present
Member-at-Large of Executive Committee, 1990-1991
Program Committee, 1988-1992; Membership Chairman, 1989-1992

Division of Chemical Marketing and Economics, member, 1986-93

Division of Professional Relations, Chair 2001, Councilor 2002-2005.

National Coil Coaters Association , 1984-93

Marketing Committee, sub-committee Sheet vs. Coil, 1987-1993
Container Coating Technical Committee, 1989-93, Chair, 1991-92;
Sub-committee On-Line Detection of Cure, 1988-93

Federation of Societies of Coatings Technology, 1984-present
Houston Coatings Society, 1988-93, 2001-present; Detroit Coatings Society, 1993-01
Journal of Coatings Technology, Editorial Review Board, 1993-present
Distinguished Lecturer, 1998-present

Second North American Conference on Coatings Science & Technology
Technical Program Co-Chairman, 1989

American Oil Chemists' Society, 1996-present.
Industrial Oil Products Division: Founding member, program committee,
Chair-Elect 2002-03, Chair, 2004-2005.

American Association for the Advancement of Science, 1970-1986, 1998-present

American Association of Industrial Crops, 1998-2000

Bioenvironmental Polymer Society, 2000-2001

 

PUBLICATIONS

 

Book Chapter

J.L. Massingill,Jr and R.S. Bauer, "Epoxy Resins", in Applied Polymer Science-21 st Century, edited by C. Craver and C. Carraher, Elsevier Science (2000).

Refereed Journals

1. W.B. Smith and J.L. Massingill, "Two Chemical Determinations of the Population of Configurations of Butadiene," J.Am. Chem. Soc ., 83 , 4301 (1968).

2. J.L. Massingill and J.E. Hodgkins, "Retention of Data--Methyl Esters of Fatty Acids on a QF-I Capillary Column," J. Gas Chromatog ., 2 , 110 (1965).

3. J.L. Massingill and J.E. Hodgkins, "Gas Chromatography of Alkaloids Using Capillary Columns and Four Packed Columns," Anal. Chem ., 37 , 952 (1965).

4. J.E. Hodgkins, S.D. Brown, and J.L. Massingill, "Two New Alkaloids in Cacti," Tetrahedron Letters , 1321, 1967.

5. J.L. Massingill and J.E. Hodgkins, "Alkaloids of Bacteria," Phytochemistry , 6 , 977 (1967).

6. S.D. Brown, J.L. Massingill, and J.E. Hodgkins, "Cactus Alkaloids," Phytochemistry , 7 , 2031 (1968).

7. J.L. Massingill, M.G. Reinecke, and J.E. Hodgkins, "A Novel Synthesis of Dihydro-p-dithins and Dihydro-1,9-dithiepins Involving Amide Leaving Groups," J. Org. Chem ., 35 , 823 (1970).

8. S.D. Brown, J.E. Hodgkins, and J.L. Massingill, "Isolation, Structure, Synthesis, and Absolute Configuration of the Cacti Alkaloid Gigantine," J. Org. Chem ., 37 , 1825 (1972).

9. P.S. Sheih and J.L. Massingill, "Fundamental Studies of Epoxy Resins for Can and Coil I. "Adhesion to Tin Free Steel," J. Coat. Tech.,62 (781), 25-30 (1990).

10. J.L. Massingill, P.S. Sheih, R.C. Whiteside, D. Benton, and D. Arnold, "Fundamental Studies of Epoxy Resins for Can and Coil II. Flexibility and Adhesion," J. Coat. Tech.,62 (781)31-39 (1990).

11. J.L. Massingill, "Adhesion and Flexibility Contributions to the Performance of Epoxy Phosphate Ester Coatings," J. Coating Tech..63 (797), 47-54 (1991).

12. J.L. Massingill and R.C. Whiteside, Jr., "Formability Improvements of Epoxy Can & Coil Coatings. I. Blends of Epoxy Phosphate Esters," J. Coatings Tech ., 65 (824 ) , 65-71(1993).

13. R. Raghavachar, R. J. Letasi, P.V. Kola, Z. Chen, and J.L. Massingill " Rubber Toughening Epoxy Thermosets With Epoxidized Crambe Oil," J.Amer.Oil Chem. Soc., 76(4), 511-516 (1999).

14. H. Zhang, J.L. Massingill, and J.T.Woo, "Low VOC, LowViscosity UV Cationic Radiation Cured Ink-Jet Ink System", J. Coating Technol. , 72 (905), 45-52 (2000)..

15. H. Zhang, J. L. Massingill, and J. T. Woo, "Zero VOC Coatings Cured by Sunlight", J. Coating Tech., 72 (903), 77-79 (2000).

16. Ramya Raghavachar, Greg Sarnecki, Jamil Baghdachi and John Massingill, "Cationic, Thermally Cured Coatings Using Epoxidized Soybean Oil", J. Coating Technol., 72 (909), 125-133 (2000).

17. Bin Zhong, Maruf Rahim and John Massingill, " Novel Coatings from Soybean Oil Phosphate Ester Polyols ", J. Coating Technol ., 73 (915), 53-57 (2001).

18. Hiren Sanghvi and John L. Massingill, Jr., "Recycling Paint Overspray", J. Coating Tech ., 74 (933), 143-145. (2002).

19. Glen Southard, Jim Woo, and John Massingill , " Synthesis of Fluorescently Tagged Polyelectrolytes", Progress in Organic Coatings, 49 (2), 160-164 (2004) .

Non-Refereed Publications

1. D.A. Hill and J.L. Massingill, "High Solids Epoxy Coatings for Structural Steel," J.Protect. Coat. and Linings , 3 (10), 47-51 (1986).

2. J.L. Massingill, "Resin Modifications Lower Epoxy Coatings VOC," Modern Paint and Coatings , 77 (12), 48 (1987).

3. J.L. Massingill, "Higher Solids, Epoxy Based Coatings," CHEMTECH , 18 (4), 236 (1988).

4. J.L. Massingill, "Epoxy," Modern Plastics Encyclopedia , 1988, pg 4.

5. J.L. Massingill, "Epoxies: Adaptable Materials for Changing Times," Materials Engineering , October, 1989, 30-33.

6. J.L. Massingill, "Higher Solids, Epoxy Coatings," Paint & Coatings Industry , 6(6), 20-24 (1990).

7. J.L . Massingill and D. Morisse-Arnold, "Properties of Solvent-Borne Epoxy Phosphate Ester Coatings," Proceedings 15th Intl. Conference in Organic Coatings Science and Technology , 1989.

8. J.L. Massingill and Y. Sayed-Sweet, "Very Low VOC Aliphatic Epoxy Coatings Based on Trimethylolpropane", Polymeric Materials: Science and Engineering , 73 , 502-3(1995).

9. R. Raghavachar, G. Sarnecki, J. A. Baghdachi and J. L. Massingill , "Cationic UV Cured Coatings Using Epoxidized Soybean Oil", RadTech Report , 12(5), 36-40 1998.

10. Z. Kuang, et al., "Epoxidized Soybean Oil as Reactive Diluent in Alkyd Coatings", Proceedings of the High, Solids, Waterborne, and Powder Coatings Symposium , New Orleans , February, 1999.

11. Z. Kuang, et al., "High Solids Alkyd Coatings Using Reactive Diluents", Proceedings of the Additives and Other Means to Enhance Coatings Technology Symposium jointly sponsored by EMU and the New York Society for Coatings Technology, April, 1999.

12. J.L. Massingill, " Epoxidized Soybean Oil - A Versatile Coating Material", Proceedings of Coatings Asia 99 Symposium , Singapore , Sept., 1999

13. B. Zhong, X. Bai, M. Rahim, and J. Massingill, "Use of Soybean Oil Phosphate Ester Polyol in UV-Cured Coatings", Proceedings 77 th Ann. Meet. Tech. Prog Fed. Soc. Coat. Technol., October, 1999.

14. B. Zhong, C. Shah, M. Rahim, and J.L. Massingill, Jr., "Novel Coatings from Soybean Oil Phosphate Esrter Polyols", Proceedings of the 27 th International Waterborne, High-Solids, & Powder Caotings Symp. , New Orleans, March 2000.

15. D. Desai, M. Rahim, J. L. Massingill, Jr., "Cationic UV Cured Coatings Using Epoxidized Soybean Oil", Proceedings of RadTech2000 , Baltimore , April 2000.

16. Vijay M Mannari and John L Massingill, Jr, " Hyperbranched Soy Alkyd Resins For Low Voc Industrial Coatings", Proceedings of the 29 th International Waterborne, High-Solids, & Powder Coatings Symp., New Orleans, Feb. 2002.

17. Vijay M Mannari and John L Massingill, Jr., "Two-Component High-Solids Polyurethane Coating Systems
Based On 'Soy-Polyol', Proceedings of the 29 th International Waterborne, High-Solids, & Powder Coatings Symp., New Orleans, Feb. 2002.

18. "Bio-Based Hyperbranched Polyols and Polymers", PMSE Division, National Meeting of the Amer. Chem. Soc., April, 2002.

19. V. M. Mannari, Y. Guo, Z. Chen+, and J. L. Massingill, Jr., "Epoxy Acid Phosphate Esters- Dispersibility And Salt Fog Resistance", Proceedings of the 30 th International Waterborne, High-Solids, & Powder Coatings Symp., New Orleans, Feb. 2003.

20. Vijaykumar Mannari, Yinzhong Guo, and John L. Massingill, Jr., " Dispersibility of phosphated bio-based hyperbranched polyols", 225th ACS National Meeting, Polymer Division, New Orleans, LA, March 2003.

Presentations

1. "High Solids Epoxy/Phenolic Coatings," Higher Solids and Water-Borne Symposium, New Orleans , 1985.

2. Plenary Lecture, "High Solids Epoxy Coatings," American Chemical Society, Division of Polymeric Materials-Science and Engineering Symposium, Anaheim , CA , 1986.

3. "Fundamental Studies of Epoxy Resins for Can and Coil II. Flexibility and Adhesion," Federation of Societies for Coating Technology, 1988.

4. Properties of Solvent-Borne Epoxy Phosphate Ester Coatings," 15th Intl. Conference on Coatings Science and Technology, Athens , Greece , 1989.

5. "Adhesion and Flexibility Contributions to the Performance of Epoxy Phosphate Ester Coatings," Federation of Societies for Coating Technology, 1990.

6. "Blends of Epoxy Phosphate Esters," First North American Conference on Coatings Science & Technology, Hilton Head, SC, 1990.

7. "Formability Improvements of Epoxy Can and Coil Coatings. I. Blends of Epoxy Phosphate Esters, Federation of Societies for Coating Technology, 1991.

8. "Epoxy Phosphate Ester Coatings," Short Course, Tokyo , February, 1991.

9. "Epoxy Phosphate Ester Coatings," Short Course, PMSE Short Course, ACS National Meeting San Francisco, 1992.

10. "Low Viscosity, Weatherable Aliphatic Epoxy Resins, Gordon Research Conference on the Science and Technology of Coatings", Poster Session, 1995.

11. "Water Determination in Paints by NIR Spectroscopy", Gordon Research conference on the Science and Technology of coatings, Poster Session, July, 1997.

12. " Rubber Toughening Epoxy Thermosets With Epoxidized Crambe Oil", Annual Meeting of Amer. Oil Chem. Society, May, 1997.

13. "Epoxidized Soybean Oil as Reactive Diluents for Epoxy and Alkyd Paints", Annual Meeting of Amer. Oil Chem. Society, May, 1997.

14. "Co-operative Research Program Involving Academia, Government, and Industry", New York Society for Coatings Technology Symposium, April, 1997.

15. "Reactive Diluents for Alkyd and Epoxy Paints", Detroit Society for Coatings Technology, March, 1997.

16. "Epoxidized Soybean Oil in alkyd Coatings", DSCT., FOCUS Conference, April, 1997.

17. "Near Infrared Determination of Water in Paints", ASTM Meeting, January, 1997.

18. "Reactive Diluents for Alkyd and Epoxy Paints", Kansas City SCT, November, 1996.

19. "Epoxidized Soybean Oil in High Solids Epoxy and Alkyd Pants" The International Conference on The Green Industrial Revolution , Association for the Advancement of Industrial Crops, Saltillo, Mexico, September, 1997.

20. "Reducing Volatile Organic Compounds (VOC) in Coatings", Exploring New Technologies for Clean Air Symposium, California Air Resources Board and EPA, September, 1997.

21. "Determination of Water in Waterborne Paint by Near Infrared Spectroscopy", Federation of Societies for Coatings Technology Annual Meeting, October, 1997.

22. "Epoxidized Soybean Oil in Cationic Cured Coatings", High Solids, Waterborne, and Powder Coatings Symposium, New Orleans , February, 1998.

23. " Coatings from Soybean Oil Polyol I. Preparation", Amer. Oil Chem. Society National Meeting, 1998.

24. "Coatings from Soybean Oil Polyol II. Water- and Solventborne Coatings", AOCS Meeting, May, 1998.

25. "Reactive Diluents for Low VOC Alkyd Coatings", Surface Coating of Metal Parts Workshops, Michigan Department of Environmental Quality, Grand Rapids, MI, September 15, 1998.

26. "Epoxidized Soybean Oil as Reactive Diluent for Alkyd Coatings", Louisville SCT, September 16, 1998 .

27. "Reactive Diluents for Low VOC Alkyd Coatings", Surface Coating of Metal Parts Workshops, Michigan Department of Environmental Quality, Southfield, MI, September, 1998.

28. "Reactive Diluent Demonstration Project in California ", CDIC Coatings Society, February, 1999.

29. "Epoxidized Soybean Oil as Reactive Diluent in Alkyd Coatings", High, Solids, Waterborne, and Powder Coatings Symposium, New Orleans , February, 1999.

30. "High Solids Alkyd Coatings Using Reactive Diluents", Additives and Other Means to Enhance Coatings Technology. Symposium sponsored by EMU and New York Society for Coatings Technology, April, 1999.

31. "Approaches to High Solids Alkyd Paints", IOP Division, American Oil Chemists Society Annual Meeting, May, 1999.

32. " Epoxidized Soybean Oil - A Versatile Coating Material", Coatings Asia 99, Singapore , Sept., 1999

33. "High Solids Alkyd Coatings Using Reactive Diluents", Shanghai Paint Industry Association, Shanghai , China , Sept., 1999.

34. "Use of Soybean Oil Phosphate Ester Polyol in UV-Cured Coatings", 77 th Ann. Meet. Tech. Prog Fed. Soc. Coat. Technol ., October, 1999.

35. "Novel Coatings from Soybean Oil Phosphate Ester Polyols", 27 th International Waterborne, High-Solids, & Powder Coatings Symp., New Orleans , March 2000.

36. "Cationic Uv Cured Coatings Using Epoxidized Soybean Oil II. Cure Speed Improvements Using Vinyl ethers and Caprolactone Acrylate", RadTech2000, April, 2000.

37. "Coating Adhesion Improvements with Soy Phosphate Ester Polyol", 2 nd International Symposium on Adhesion Aspects of Polymeric Coatings, May, 2000.

38. "Soybean Oil Polyol for Plastics and Coatings", Annual Meeting American Oil Chemists Society, May 2001.

39. "Epoxidized Soybean Oil- A Versatile Industrial Raw Material", I&EC Division, National Meeting of the Amer. Chem. Soc., August 2001.

40. "Alkyd Coatings from Hyperbranched Polyols", 79 th Ann. Meet. Tech. Prog Fed. Soc. Coat. Tech ., Oct. 2001.

41. " Hyperbranched Soy Alkyd Resins For Low Voc Industrial Coatings", 29 th International Waterborne, High-Solids, & Powder Coatings Symp., New Orleans , Feb. 2002.

42. "Bio-Based Hyperbranched Polyols and Polymers", PMSE Division, National Meeting of the Amer. Chem. Soc., April, 2002.

43. "Preparation of Soybean Oil Phosphate Ester Polyol", Annual Meeting American Oil Chemists Society, May 2002.

44. " Dispersibility of phosphated bio-based hyperbranched polyols", 225th ACS National Meeting, PMSE Division, New Orleans , LA , March 2003.

Company Central Research Index Reports: 49

Patents

U.S. Patents- 4,362,848; 4,319,009; 4,387,182; 4,389,512; DCPD Acrylate, 1976.
U.S. Patent- 4,623,701; Polyfunctional Epoxy Resins, 1983.
U.S. Patent- 4,579,959; Acetylenic Compounds, 1984.
U.S. Patents- 4,820,784; 4,835,225; Aliphatic/Aromatic Hybrid Resins, 1989.
U.S. Patent- 5,086,094; Epoxy Phosphate Esters, 1989.

Company Confidential Reports: 49

Theses Supervised (Eastern Michigan University Polymers & Coatings Program)

  1. Zhe Li, "The Use of Conjugated Soybean Oil in Coatinga", 2000
  2. Pranav Mathuria, "Soybean Oil Phosphate Ester Polyol Synthesis", 2000.
  3. Bin Zhong, "Coatings From Novel Soybean Oil Phosphate Ester Polyol", 2000.
  4. Xiafong Bai, "Water-Reducible Coatings Based On Epoxidized Soybean Oil Phosphate Ester Polyols, 2000.
  5. Ashifali Saiyad, "ESBO as Reactive Diluent for High Solids Coatings", 2000.
  6. Hiren Arvind Sanghvi,"Use Of Epoxidized Soybean Oil As A Reactive Diluent In Water Reducible Alkyd Paint and Utilization Of Paint Residue", 1999.
  7. Mahrokh Soltani, "Reducing VOC of Short Oil Alkyd Coatings with Epoxidized Soybean Oil as Reactive Diluent", 1999.
  8. Denis Desai, "Use Of Soybean Oil Derivatives In UV Cured Coatings", 1999.
  9. Chirag Shah, "Modified Solvent-Borne Alkyd Coatings Based On Soybean Oil As Reactive Diluent",1999.
  10. Zueting Qiu, "Analysis of Water in Paints by Gas Chromatography and Near Infrared Spectroscopy", 1999.
  11. ASTM Method modified, summer 2000
  12. Papinporn S.Chutayothin, "New Soybean Oil Drying Oils for Alkyd Resin Used in Air-Dried Coatings, 1998.
  13. Zhonghui Kuang, "Property Improvements in High Solids Alkyd Coatings- Epoxidized Soybean Oil as Reactive Diluent", 1998.
  14. Ramya Raghavachar, "Role Of Epoxidized Vegetable Oils In Rubber-Toughening Of Epoxy Thermosets And High-Solids Epoxy Coatings", 1997.
  15. Shijun Wang, "Determination of Water in Paints by Gas Chromatography and Near Infrared Technique", 1997.
  16. Zheng Wu, "Determination Of Water In Paint Volatiles Utilizing Gas Chromatography", 1996.
  17. Purnima Dalvi, "Epoxidized Vegetable Oils as Reactive Diluents for Epoxy and Alkyd Coatings, 1996.
  18. Richard John Letasi, "Two-Phase Epoxy Thermosets with Epoxidized Crambe and Rapeseed Oils", 1995.

RESEARCH GRANTS

  1. Southern California Edison , $75,000. "Low VOC, Low Viscosity Aliphatic Epoxy Wood Coating", 1993.
  2. NSF Industry/ University Cooperative Research Center in Coatings, $140,000, Water in Paints. 94- Œ00.
  3. USDA COOP Heade Program, $30,000, "Epoxidized Vegetable Oils For Improved Commercial Epoxy Thermosets", 1994 (inherited).
  4. USDA COOP, $120,000, "Epoxidized Soybean as a Reactive Diluent in Alkyd and Epoxy Coatings", 1994 (inherited).
  5. South Coast Air Quality Management District, $60,000, "Development Of Low Cost Substitutes For Vernonia Oil As Reactive Diluents With Alkyd And Epoxy Coatings", 1995.
  6. NSF I/UCRCC, $10,000, Exploratory grant for "Resins from Sugars", 1995.
  7. NSF I/UCRCC, $60,000 "Resins from Sugars", 1995.
  8. Environmental Protection Industries, $24,000, "Recycling Auto Paint Overspray", 1996.
  9. United Soybean Board, $400,000, "Improved Alkyd Coatings Based On Soybean Oil ", 1996.
  10. South Coast Air Quality Management District, $40,000, " California Aim Paint Survey", 1996.
  11. United Soybean Board, $65,000, "Conjugated Soybean Oil in Coatings and Inks", 1997-01. (with Iowa State University ).
  12. NSF I/UCRCC, $100,000, "Adsorption Behavior Of Anionic Polymers", 1997-99 (with Lehigh Univ. )
  13. United Soybean Board, $337,000, "Improved Coatings Based on Soybean Oil", 1998.
  14. Amoco Chemical Company, $68,000, "Hyperbranched Polyols", 1997.
  15. NSF I/UCRCC, $30,000, "UV-Curable Inkjet Ink", 1997.
  16. NSF I/UCRCC, $30,000, "Visible Light Cured Epoxy", 1998.
  17. Michigan Soybean Promotion Committee, $30,000, "Soy Polyol", 1998.
  18. United Soybean Board, $148,800, "Soy Polyol in Coatings, Textiles, and Concrete", 2000.
  19. Iowa Soybean Promotion Board, $67,000, "Soy Polyol in Ballpoint Pen Ink", 2000.
  20. Michigan Soybean Promotion Committee, $20,000, "Feasibility Study for Soy PVC Plasticizer", 2000.
  21. Navy SBIR with SMRC, $70,000, "One Part Polysulfiide Sealants", 2001.
  22. National Academy of Science, $84,000, "Waterproofing Concrete " (with Univ. of Texas )
  23. United Soybean Board, $50,000, matching funds for item 22.
  24. National Science Foundation SBIR Phase I, $33,000, "New Fiber Reactor for Organic Synthesis". 2003
  25. California Air Resources Board, $99,200, "High Performance Low VOC Coatings for 2006", 2003.
  26. United Soybean Board, $112,000, "Soy Tackifier for Adhesives", 2003.
  27. USDA, SBIR with CBDC, $80,000, "Soy Primary Plastizier, 2004.